CH3NH3PbI3 perovskite single crystals: surface photophysics and their interaction with the environment† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c5sc02542g Click here for additional data file.
نویسندگان
چکیده
†Center for Nano Science and Technology @Polimi, Istituto Italiano di Tecnologia, via Giovanni Pascoli 70/3, 20133, Milan, Italy. ┴Dipartimento di Fisica, Politecnico di Milano, Piazza L. da Vinci, 32, 20133 Milano, Italy ‡Department of Chemistry, Stanford University, 337 Campus Drive, Stanford, California 94305, USA ◊ Computational Laboratory for Hybrid/Organic Photovoltaics (CLHYO), CNR-ISTM, I-06123, Perugia, Italy ║ Department of Materials Science and Engineering, Stanford University, 476 Lomita Mall, Stanford, California 94305, USA
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CH3NH3PbI3 perovskite single crystals: surface photophysics and their interaction with the environment.
Here we identify structural inhomogeneity on a micrometer scale across the surface of a CH3NH3PbI3 perovskite single crystal. At the crystal edge a local distortion of the crystal lattice is responsible for a widening of the optical bandgap and faster photo-carrier recombination. These effects are inherently present at the edge of the crystal, and further enhanced upon water intercalation, as a...
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عنوان ژورنال:
دوره 6 شماره
صفحات -
تاریخ انتشار 2015